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A Summary of Physical and Chemical Properties of Methanol, Gasoline (BTEX), and Benzene

Physical and chemical properties

Methanol

Gasoline

Benzene

Molecular weight [g/mole]

32.04

~100 (c)

78.11 (c)

Elemental composition by weight
% Oxygen
% Carbon
% Hydrogen

50%
37.5%
12.5%

(mix of C4 to C14 hydrocarbons)

0%
92%
8%

Specific gravity

0.7915 @ 60¡F (f)

0.72-0.78 (c)

0.88(c)

Boiling point [¡C]

64.7

27-225 (b)

80.1(c)

Water solubility [mg/L]

miscible

100-200 (c)

1,780

Vapor pressure
[mm Hg] (@ 25¡C)
[psi] (@ 100¡F) (e)

126
4.63

--
7-15

76, 95 (c)
---

Heat of combustion [kJ/kg] (b)

19,930

43,030

---

Henryâs Law constant [atm m3 g-1 mole-1]

4.55 x 10-6
4.42 x 10-6 (c)

---

5.43 x 10-3 (c)

Henryâs Law constant [-] @ 25°C

1.087 x 10-4

---

0.22

Liquid Dispersion Coefficient @ [m2/s] 25°C

1.65 x 10-9

---

9.95 x 10-10

Log Koc

0.921
0.44 (c)

---

1.8-1.99
1.50-2.16 (c)

Log Kow

-0.77
-0.75(c)

---

2.13
1.56-2.15 (c)

Flammability Limits (b):

 

 

Lower (LFL)
  Volume percent
  Temperature (¡C)

6.0
7

1.4
-43

---

Upper (UFL)
  Volume percent
  Temperature (¡C)

36.5
43

7.6
-30 to-12

---

Flash Point (¡C)

12¡C (54¡F) (a)

-43 (¡F)

---

Vapor Density @ 1 atm; 10°C (b)

1.4

2-5

3.4

(a) Merck Index, 1989; (b) Machiele, 1989; (c)Zogorski et al., 1997; (d) Bauman, 1989; (e) USDOE, 1991;



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